HR: 1330h
AN: U32A-0034    [PDF]
TI: Environmental and Health Benefits and Risks of a Global Hydrogen Economy
AU: * Dubey, M
EM: dubey@lanl.gov
AF: Los Alamos National Laboratory, D462, Los Alamos, NM 87545 United States
AU: Horowitz, L W
EM: Larry.Horowitz@noaa.gov
AF: GFDL, NOAA, Box 308 Princeton University, Princeton, NJ 08542 United States
AU: Rahn, T A
EM: trahn@lanl.gov
AF: Los Alamos National Laboratory, D462, Los Alamos, NM 87545 United States
AU: Kinnison, D E
EM: dkin@ucar.edu
AF: NCAR, 1850 Table Mesa Drive, Boulder, CO 80303 United States
AB: Rapid development in hydrogen fuel-cell technologies will create a strong impetus for a massive hydrogen supply and distribution infrastructure in the coming decades. Hydrogen provides an efficient energy carrier that promises to enhance urban and regional air quality that will benefit human health. It could also reduce risks of climate change if large-scale hydrogen production by renewable or nuclear energy sources becomes viable. While it is well known that the byproduct of energy produced from hydrogen is water vapor, it is not well known that the storage and transfer of hydrogen is inevitably accompanied by measurable leakage of hydrogen. Unintended consequences of hydrogen leakage include reduction in global oxidative capacity, changes in tropospheric ozone, and increase in stratospheric water that would exacerbate halogen induced ozone losses as well as impact the earth's radiation budget and climate. Stratospheric ozone depletion would increase exposure to harmful ultraviolet radiation and increased risk to melanoma. We construct plausible global hydrogen energy use and leak scenarios and assess their impacts using global 3-D simulations by the Model for Ozone And Related Trace species (MOZART). The hydrogen fluxes and photochemistry in our model successfully reproduce the contemporary hydrogen cycle as observed by a network of remote global stations. Our intent is to determine environmentally tolerable leak rates and also facilitate a gradual phasing in of a hydrogen economy over the next several decades as the elimination of the use of halocarbons gradually reduces halogen induced stratospheric ozone loss rates. We stress that the future evolution of microbial soil sink of hydrogen that determines its current lifetime (about 2 years) is the principal source of uncertainty in our assessment. We propose global monitoring of hydrogen and its deuterium content to define a baseline and track its budget to responsibly prepare for a global hydrogen economy.
DE: 0300 ATMOSPHERIC COMPOSITION AND STRUCTURE
DE: 0317 Chemical kinetic and photochemical properties
DE: 0400 Biogeosciences
SC: U
MN: 2003 Fall Meeting