HR: 1340h
AN: H23A-1413 [Abstracts]
TI: Experimental Investigation of DNAPL Mass Flux Reduction as a Function of Source Zone Mass
Removal
AU: * DiFilippo, E L
EM: edifilip@hwr.arizona.edu
AF: University of Arizona, Department of Hydrology and Water Resources
1133 E. North Campus Drive
Harshbarger Building, P.O. Box 210011, Tucson, AZ 85721
United States
AU: Brusseau, M L
EM: brusseau@ag.arizona.edu
AF: University of Arizona, Department of Soil, Water and Environmental Science
P.O. Box 210038, Tucson, AZ 85721-0038
United States
AU: Brusseau, M L
EM: brusseau@ag.arizona.edu
AF: University of Arizona, Department of Hydrology and Water Resources
1133 E. North Campus Drive
Harshbarger Building, P.O. Box 210011, Tucson, AZ 85721
United States
AU: Oostrom, M
EM: mart.oostrom@pnl.gov
AF: Pacfic Northwest National Laboratory, Environmental Technology Division, Richland, WA 99352
AU: Wietsma, T W
EM: wietsma@pnl.gov
AF: Pacific Northwest National Laboratory, Environmental Molecular Science Laboratory, Richland, WA 99352
United States
AB:
Several in-situ technologies have been developed for the remediation of DNAPL source zones (e.g., surfactant/cosolvent
flushing, chemical oxidation). Generally, the application of such technologies results in mass reduction, rather than
complete mass removal. Determining the relationship between mass flux reduction and source zone mass removal can support the
cost benefit analysis of partial source zone mass removal. Intermediate-scale flow cell dissolution experiments were
conducted using silica sands and carbon tetrachloride to investigate this relationship. Source zones comprised of either
residual or pooled DNAPL in physically heterogeneous systems were examined. The mass flux of contaminant down gradient of the
source zone was monitored by measuring effluent concentration and flow rate at eight discrete vertical locations. These
eight outlet ports provide a depth concentration profile for the total outflow. In-situ DNAPL saturations were obtained from
dual-energy gamma radiation measurements taken throughout the course of the experiments.
DE: 1829 Groundwater hydrology
DE: 1831 Groundwater quality
DE: 1832 Groundwater transport
SC: Hydrology [H]
MN: Fall Meeting 2005