HR: 12:05h
AN: PP42A-08    [Abstracts]
TI: Paleo-Productivity across the Paleocene-Eocene Thermal Maximum, Walvis Ridge Transect (ODP Sites 1262, 1263, and 1266)
AU: * Chun, C O
EM: cchun@ucsc.edu
AF: Ocean Sciences/Institute of Marine Sciences, 1156 High Street, Santa Cruz, CA 95064 United States
AU: Delaney, M L
EM: delaney@ucsc.edu
AF: Ocean Sciences/Institute of Marine Sciences, 1156 High Street, Santa Cruz, CA 95064 United States
AU: Zachos, J C
EM: jzachos@pmc.ucsc.edu
AF: Earth Sciences/Institute of Marine Sciences, 1156 High Street, Santa Cruz, CA 95064 United States
AB: Walvis Ridge transect (Ocean Drilling Program (ODP) Leg 208) provides the first high-resolution depth-transect of deep-sea sediments recovered from the south Atlantic across the P/E boundary. A geographically restricted depth transect (~ 2.2 km, water depths between 2500 and 4770 m) allows us to constrain the surface waters by assuming marine productivity conditions in the overlying water column are similar across all sites. The sediment record will reveal variations for processes that are water-depth dependent. We use the geochemical tracers; biogenic barium, phosphorus, calcium carbonate, and the redox sensitive trace elements manganese and uranium, to reconstruct nutrient burial, paleoproductivity, and bottom water redox chemistry across the Paleocene-Eocene Thermal Maximum (PETM). We calculate our concentrations on a calcium carbonate-free basis to account for dilution by non-carbonate sediments. Trace metal enrichment factors (EFs) are calculated relative to bulk crustal averages. We chose three sites from the depth transect: the shallowest (Site 1263, 2717 m water depth), an intermediate site (Site 1266, 3798 m water depth), and the deepest site (Site 1262, 4755 m water depth). We sampled each site at a sample resolution of ~ 1-2 kyr for 5 m.y. centered at 55 Ma. Uranium EFs at the shallow site exhibits values ~ 5 pre-event and drop to values near crustal averages during and after the carbon isotope excursion (CIE). No dramatic changes in U EFs across the P/E boundary are recorded at the deep and intermediate sites. Mn EFs range between 2.9 -8.6 prior to the event across all three sites, suggesting an oxygenated depositional environment. At the boundary, Mn EFs drop to crustal averages at all sites, then gradually return to pre-event values, indicating more reducing environments during the CIE, a possible explanation for the benthic extinction event (BEE) observed across this transect. Ba excess and reactive phosphorus exhibit decreased concentrations during the CIE with gradual return to pre-event values at the shallowest and deepest sites. We will compare the paleo-productivity and redox chemistry response at the Walvis Ridge sites across the PETM.
DE: 4825 Geochemistry
DE: 4845 Nutrients and nutrient cycling (0470, 1050)
DE: 4875 Trace elements (0489)
DE: 4924 Geochemical tracers
DE: 4948 Paleocene/Eocene thermal maximum
SC: Paleoceanography and Paleoclimatology [PP]
MN: Fall Meeting 2005