HR: 10:35h
AN: SA52A-02 INVITED     [Abstracts]
TI: Photochemistry of Planetary Atmospheres
AU: * Yung, Y L
EM: yly@gps.caltech.edu
AF: Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, 91125
AB: The Space Age started half a century ago. Today, with the completion of a fairly detailed study of the planets of the Solar System, we have begun studying exoplanets (or extrasolar planets). The overriding question in is to ask whether an exoplanet is habitable and harbors life, and if so, what the biosignatures ought to be. This forces us to confront the fundamental question of what controls the composition of an atmosphere. The composition of a planetary atmosphere reflects a balance between thermodynamic equilibrium chemistry (as in the interior of giant planets) and photochemistry (as in the atmosphere of Mars). The terrestrial atmosphere has additional influence from life (biochemistry). The bulk of photochemistry in planetary atmospheres is driven by UV radiation. Photosynthesis may be considered an extension of photochemistry by inventing a molecule (chlorophyll) that can harvest visible light. Perhaps the most remarkable feature of photochemistry is catalytic chemistry, the ability of trace amounts of gases to profoundly affect the composition of the atmosphere. Notable examples include HOx (H, OH and HO2) chemistry on Mars and chlorine chemistry on Earth and Venus. Another remarkable feature of photochemistry is organic synthesis in the outer solar system. The best example is the atmosphere of Titan. Photolysis of methane results in the synthesis of more complex hydrocarbons. The hydrocarbon chemistry inevitably leads to the formation of high molecular weight products, giving rise to aerosols when the ambient atmosphere is cool enough for them to condense. These results are supported by the findings of the recent Cassini mission. Lastly, photochemistry leaves a distinctive isotopic signature that can be used to trace back the evolutionary history of the atmosphere. Examples include nitrogen isotopes on Mars and sulfur isotopes on Earth. Returning to the question of biosignatures on an exoplanet, our Solar System experience tells us to look for speciation that reveals the reaction pathways, disequilibrium forcing (what portion of the irradiance of the central star is harvested?) and isotopic signatures that are fingerprints of photochemistry and biochemistry.
DE: 0343 Planetary atmospheres (5210, 5405, 5704)
DE: 5210 Planetary atmospheres, clouds, and hazes (0343)
DE: 5405 Atmospheres (0343, 1060)
DE: 5445 Meteorology (3346)
DE: 6281 Titan
SC: SPA-Aeronomy [SA]
MN: Fall Meeting 2005