HR: 0800h
AN: A21B-0739 [Abstracts]
TI: Seasonal Variability of H$_{2}$O and O$_{3}$ in the UT/LS and Extent of the Extra-tropical Mixing Layer
Based on Airborne SPURT Measurements
AU: * Krebsbach, M
EM: m.krebsbach@fz-juelich.de
AF: Research Centre Juelich GmbH, Institute for Chemistry and Dynamics of the Geosphere I: Stratosphere,
Juelich, 52428
Germany
AU: Guenther, G
EM: g.guenther@fz-juelich.de
AF: Research Centre Juelich GmbH, Institute for Chemistry and Dynamics of the Geosphere I: Stratosphere,
Juelich, 52428
Germany
AU: Spelten, N
EM: n.spelten@fz-juelich.de
AF: Research Centre Juelich GmbH, Institute for Chemistry and Dynamics of the Geosphere I: Stratosphere,
Juelich, 52428
Germany
AU: Schiller, C
EM: c.schiller@fz-juelich.de
AF: Research Centre Juelich GmbH, Institute for Chemistry and Dynamics of the Geosphere I: Stratosphere,
Juelich, 52428
Germany
AB:
The data set presented in this study was obtained during the airborne project SPURT (german: trace gas transport in the
tropopause region). The high-resolution \emph{in situ} measurements of a large set of trace gases, thereunder total water
(H$_{2}$O) and ozone (O$_{3}$), took place over Europe between November $2001$ and July $2003$. Each annual season was
investigated within $2$ campaigns in the region around the polar jet covering a broad latitude range between $20-80$^\circ$N.
Based upon this data set, we derived a seasonal climatology and characteristics of trace gas distributions, their gradients
and variability in that region. Significantly enhanced H$_{2}$O mixing ratios of several $10$\ ppmv near the tropopause and
even higher up in the LS have been detected during all seasons. To get a comprehensive insight into processes, ranging and
variability of the measured parameters in the investigated area, correlations, distributions as well as probability density
distributions (PD) of the \emph{in situ} measured trace gases H$_{2}$O and O$_{3}$ were determined by using chemical, thermal
and dynamical coordinates (e.g.\ potential temperature, potential vorticity, distance to the local tropopause, distance to
the jet stream maximum wind speeds, equivalent latitude). The PDs serve as a tool to transform localised aircraft data to a
more comprehensive view of the tropopause region. It appears that both trace gases show most compact distributions and are
best correlated in the view of potential vorticity and distance to the local tropopause. The seasonal cycles of H$_{2}$O and
O$_{3}$ in the UT and LS are also evident in the PDs. An extra-tropical mixing layer following the shape of the tropopause
and/or surfaces of potential vorticity was identified. Based on Lagrangian studies this layer is supposed to be influenced by
transport processes on time scales of days to weeks. From tracer-tracer-correlations the extent of this layer could be
estimated to range from the local tropopause to approximately $8-9$\ PVU, independent from season. By long-term simulations
using the J\"{u}lich CLaMS (Chemical Lagrangian Model of the Stratosphere) the tropospheric influence with enhanced H$_{2}$O
values even beyond this layer could be reproduced which originates from transport on longer time scales.
DE: 0341 Middle atmosphere--constituent transport and chemistry (3334)
DE: 0343 Planetary atmospheres (5405, 5407, 5409, 5704, 5705, 5707)
DE: 0365 Troposphere--composition and chemistry
SC: Atmospheric Sciences [A]
MN: 2004 AGU Fall Meeting