HR: 1340h
AN: V13A-1453 [Abstracts]
TI: Petrology and Geochemistry of Eclogite Xenoliths from the Colorado Plateau: Implications for the
Evolution of Subducted Oceanic Crust
AU: * Usui, T
EM: tusui@misasa.okayama-u.ac.jp
AF: The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Study of the Earth's
Interior, Okayama University, Yamada 827, Misasa, Tottori, 682-0193
Japan
AU: Nakamura, E
EM: eizonak@misasa.okayama-u.ac.jp
AF: The Pheasant Memorial Laboratory for Geochemistry and Cosmochemistry, Institute for Study of the Earth's
Interior, Okayama University, Yamada 827, Misasa, Tottori, 682-0193
Japan
AU: Helmstaedt, H
EM: helmstaedt@geol.queensu.ca
AF: Department of Geological Sciences and Geological Engineering, Queen's University, Kingston, Ontario,
K7L 3N6
Canada
AB:
Eclogite xenoliths from the Colorado Plateau, interpreted as representing fragments of the subducted Farallon plate, are used
to infer the evolution of trace element and isotopic compositions of oceanic crust subducted into the subarc mantle. The
xenoliths consist of almandine-rich garnet, Na-clinopyroxene, lawsonite and zoisite with minor amounts of phengite, rutile,
pyrite and zircon. They have essentially basaltic bulk-rock major element compositions, except for significantly higher
Na$_{2}$O, but similar K$_{2}$O, with increasing SiO$_{2}$ contents, compared to altered MORB. These major element
characteristics are explained by spilitization/albitization during hydrothermal alteration at a mid-ocean ridge and by
subduction zone metasomatism in the forearc region.
Whole-rock trace elements and Sr, Nd, and Pb isotopic compositions of the xenoliths are variable and exhibit significantly
enriched characteristics compared to altered MORB, except for similar Zr/Hf ratios of 36.9 to 37.6. Mass balance for the
Colorado Plateau eclogite xenoliths can be achieved for 26 trace elements, Rb, Cs, Sr, Ba, Y, REE, HFSE (Zr, Hf, Nb, and Ta),
Pb, Th and U. The mass balance calculations and mineralogical observations corroborate that whole-rock chemistry of the
xenoliths were contaminated by near-surface processes after eruption and limited interaction with the serpentinized
ultramafic microbreccia host magma. Thus, Sr, Nd and Pb isotopic compositions of separated minerals from the xenoliths were
measured to avoid these secondary effects; these separates yield distinctively enriched isotopic compositions in the range of
0.70502 to 0.70590 for $^{87}$Sr/$^{86}$Sr, -1.5 to -3.1 for $\epsilon$Nd and 18.928 to 19.052 for $^{206}$Pb/$^{204}$Pb.
This suggests that the xenoliths were metasomatized by a fluid equilibrated with the sedimentary layer probably covering the
Farallon plate in the forearc region. This metasomatism resulted in the xenoliths acquiring distinctively enriched isotopic
compositions compared with those of altered MORB. Some of the distinct isotopic signatures observed in OIBs compared to
those from MORBs have been interpreted as a result of oceanic sediment subducted deep into the mantle. Our results, on the
contrary, suggest an alternative possibility that these anomalous isotopic reservoirs in the mantle are formed by the
subduction of oceanic crust modified by the metamorphic fluid from the covering sedimentary rocks.
DE: 3660 Metamorphic petrology
DE: 1040 Isotopic composition/chemistry
DE: 1010 Chemical evolution
SC: Volcanology, Geochemistry, Petrology [V]
MN: 2004 AGU Fall Meeting