HR: 0800h
AN: V21A-0594    [Abstracts]
TI: Geochemical constraints on the origin of serpentinization of oceanic mantle
AU: * Li, Z
EM: zxli@rice.edu
AU: Lee, C A
EM: ctlee@rice.edu
AB: The lower seismic zone of double seismic zones in subducting oceanic lithosphere is suggested to be a result of serpentine or chlorite dehydration in the lithospheric mantle (Hacker et al., 2003). However, the mechanism by which oceanic lithospheric mantle is serpentinized is unclear. One way is through hydrothermal circulation where the lithospheric mantle represents part of the circuit through which seawater passes and then returns to the ocean. Another way is to inject seawater into the lithospheric mantle through fractures in the overlying crust without having a return path of water to the ocean. The two mechanisms differ in that the former is an open system process whereas the latter is a closed system process in which the mantle serves as a ­øsponge­ñ for water. Identifying the dominant process is important. For example, if the mantle is part of a hydrothermal circulation cell, the interaction of seawater with the mantle will influence the composition of seawater. This also has important implications for the heat flow out of seafloor. On the other hand, if serpentinization occurs by a closed system process, there will be no influence on seawater composition. Previous studies have suggested that serpentinization of ophiolite bodies was an isochemical process, hence closed system, but it was not clear in these studies whether serpentinization occurred in situ in the oceanic lithosphere. To better understand serpentinization processes in the oceanic lithosphere, we investigated a continuous transition zone of relatively unaltered harzburgite to completely serpentinized harzburgite in the Feather River Ophiolite in northern California. These samples are highly enriched in Na, K, Rb, Cs, U, and Sr, which strongly suggests that serpentinization occurred while the oceanic lithosphere was beneath the ocean. All samples (n=19) have Al2O3 contents ranging from 0.6 to 2.5 wt.% and have extremely depleted light rare-earth element abundances, indicating that these samples are cpx-free harzburgites, which have experienced roughly 20 to 35% melt extraction. The degree of serpentinization was quantified using the concentration of magnetite, a by-product of serpentinization. The lack of antigorite suggests that serpentinization occurred at temperatures lower than 300 C. By comparing Cr and Cr/Al systematics to that predicted from theoretical partial melting calculations and empirical relationships in unaltered peridotite xenoliths, it is shown that Cr and Al are immobile. Al content was thus used to determine the composition of the protolith, which allows us to estimate the amount of depletion/enrichment of a given element by processes other than melt depletion. Most of the harzburgites show no evidence for mantle metasomatism as evidenced by extreme depletions in LREE elements. Consistent with previous studies, we find no depletions in Mg, Fe, or Ca. As seawater is undersaturated in Mg-bearing minerals, an open system process would yield progressive depletion of Mg as is seen in abyssal peridotites, which have been weathered by seawater at the bottom of the seafloor (e.g., Snow et al. 1995). Collectively, this suggests that, except for the addition of seawater and its constituents, serpentinization of the Feather River Ophiolite, was a closed system process. By combining these observations with the results of our field mapping project, we suggest that serpentinization of the lithospheric mantle occurs by local introduction of seawater through fractures extending from the crust and into the mantle. We find no evidence that serpentinized zones in oceanic lithospheric mantle represents an extremely deep hydrothermal circulation cell.
DE: 1749 Volcanology, geochemistry, and petrology
SC: Volcanology, Geochemistry, Petrology [V]
MN: 2004 AGU Fall Meeting