HR: 15:00h
AN: V33F-05    [Abstracts]
TI: High salinity volatile phases in magmatic Ni-Cu-platinum group element deposits
AU: * Hanley, J J
EM: hanley@geology.utoronto.ca
AF: Department of Geology, University of Toronto, 22 Russell Street, Toronto, ON M5S3B1 Canada
AU: Mungall, J E
EM: mungall@geology.utoronto.ca
AF: Department of Geology, University of Toronto, 22 Russell Street, Toronto, ON M5S3B1 Canada
AB: The role of "deuteric" fluids (exsolved magmatic volatile phases) in the development of Ni-Cu-PGE (platinum group element) deposits in mafic-ultramafic igneous systems is poorly understood. Although considerable field evidence demonstrates unambiguously that fluids modified most large primary Ni-Cu-PGE concentrations, models which hypothesize that fluids alone were largely responsible for the economic concentration of the base and precious metals are not widely accepted. Determination of the trace element composition of magmatic volatile phases in such ore-forming systems can offer considerable insight into the origin of potentially mineralizing fluids in such igneous environments. Laser ablation ICP-MS microanalysis allows researchers to confirm the original metal budget of magmatic volatile phases and quantify the behavior of trace ore metals in the fluid phase in the absence of well-constrained theoretical or experimental predictions of ore metal solubility. In this study, we present new evidence from major deposits (Sudbury, Ontario, Canada; Stillwater Complex, Montana, U.S.A.) that compositionally distinct magmatic brines and halide melt phases were exsolved from crystallizing residual silicate melt and trapped within high-T fluid conduits now comprised of evolved rock compositions (albite-quartz graphic granite, orthoclase-quartz granophyre). Petrographic evidence demonstrates that brines and halide melts coexisted with immiscible carbonic phases at the time of entrapment (light aliphatic hydrocarbons, CO$_{2}$). Brine and halide melt inclusions are rich in Na, Fe, Mn, K, Pb, Zn, Ba, Sr, Al and Cl, and homogenize by either halite dissolution at high T ($\sim$450-700$\deg$C) or by melting of the salt phase (700-800$\deg$C). LA-ICPMS analyses of single inclusions demonstrate that high salinity volatile phases contained abundant base metals (Cu, Fe, Sn, Bi) and precious metals (Pt, Pd, Au, Ag) at the time of entrapment. Notably, precious metal concentrations in the inclusions are comparable to and often exceed the economic concentrations of the metals within the ores themselves. As a consequence of these results, current genetic models must be revised to consider the role played by hydrous saline melts and magmatic brines in deposit development, and the potential for interaction and competition between sulfide liquids (or PGE-bearing sulfide minerals) and hydrosaline volatiles for available PGE and Au in a crystallizing mafic igneous system must be critically evaluated.
DE: 3640 Igneous petrology
DE: 3694 Instruments and techniques
DE: 1060 Planetary geochemistry (5405, 5410, 5704, 5709, 6005, 6008)
DE: 1065 Trace elements (3670)
DE: 1010 Chemical evolution
SC: Volcanology, Geochemistry, Petrology [V]
MN: 2004 AGU Fall Meeting