HR: 14:35h
AN: V33E-04 [Abstracts]
TI: The role of electron microprobe mapping and dating in tectonic geochronology
AU: * Williams, M L
EM: mlw@geo.umass.edu
AF: Department of Geosciences
University of Massachusetts, 611 North Pleasant St, Amherst, MA 01003, United States
AU: Jercinovic, M J
EM: mjj@geo.umass.edu
AF: Department of Geosciences
University of Massachusetts, 611 North Pleasant St, Amherst, MA 01003, United States
AU: Dumond, G
EM: gdumond@geo.umass.edu
AF: Department of Geosciences
University of Massachusetts, 611 North Pleasant St, Amherst, MA 01003, United States
AU: Mahan, K H
EM: mahank@colorado.edu
AF: Dept. of Geological Sciences
University of Colorado, Campus Box 399, 2200 Colorado Ave, Boulder, CO 80309, United States
AU: Flowers, R M
EM: Rebecca.Flowers@Colorado.EDU
AF: Dept. of Geological Sciences
University of Colorado, Campus Box 399, 2200 Colorado Ave, Boulder, CO 80309, United States
AB:
Electron microprobe geochronology occupies a special niche within the spectrum of geochronological
techniques and may be particularly relevant to the question, "What are we dating?" The technique was originally
envisioned to be a low-cost, reconnaissance dating tool, opening low-resolution geochronology to a large
number of researchers. However, more than a decade of research has shown that, when used in a
reconnaissance fashion (i.e. using major-element analytical techniques for trace-element analysis) uncertainties
are unsuitably large (several 10s of m.y. or more) for solving most tectonic problems. Using trace element
analytical techniques (background modeling, interference correction, highly conductive coating, multi-analysis
measurement, etc.) precision and accuracy are dramatically increased, but analysis time and cost are also
increased, challenging the “quick, cheap, and easy” description. The power of microprobe geochronology
comes from the spatial resolution and the natural integration with compositional data. High-resolution
compositional mapping is valuable for all in-situ geochronology. Large area maps provide petrologic and textural
context for chronometer phases; small scale maps illuminate the history of the chronometers themselves.
Compositional maps associated with monazite are particularly informative, but examples from the East
Athabasca granulite terrane using zircon, titanite, and rutile will be discussed. Most monazite crystals are 30μ or
less and most have several compositional domains. Rim compositions and dates are particularly critical
because they can commonly be tied to reactions and to matrix texture and fabric. Commonly, rims and internal
sub domains are several microns in width and can only be analyzed by electron probe. Y has been widely used to
tie monazite to Grt growth or breakdown, but current studies use a suite of trace and REE (Y, Sm, Nd, Ca, Eu, Gd,
etc) to tie monazite into chemical reactions. A rapidly growing application involves detrital and authigenic monazite
(and xenotime). Detrital grains that can be linked with source terrains can have very thin authigenic or
metamorphic rims dating digenesis or early metamorphism. The rims involve reactions with monazite and
surrounding phases that constrain depositional or metamorphic conditions and fluid compositions. Because
concordancy cannot be tested, microprobe monazite applications in the Athabasca granulite terrain are strongest
in combination with high-resolution U-Pb TIMS data. Microprobe dates constrain the age of specific deformation
or metamorphic processes within the context of the overall high-precision geochronologic spectrum.
DE: 1100 GEOCHRONOLOGY
DE: 3600 MINERALOGY AND PETROLOGY
DE: 8103 Continental cratons
SC: Volcanology, Geochemistry, Petrology [V]
MN: 2007 Fall Meeting