HR: 08:45h
AN: NB21F-02    [Abstracts]
TI: Effects of Concrete Channels on Stream Biogeochemistry, Maryland Coastal Plain
AU: * Prestegaard, k L
EM: kpresto@geol.umd.edu
AF: University of Maryland, Department of Geology , College Park, MD 20742 United States
AU: Gilbert, L
AF: University of Maryland, Department of Geology , College Park, MD 20742 United States
AU: Phemister, k
AF: University of Maryland, Department of Geology , College Park, MD 20742 United States
AB: In the 1950's and 60's, extensive networks of cement-lined channels were built in suburban watersheds near Washington, D.C. to convey storm water to downstream locations. These cement-lined stream channels limit interactions between surface and groundwater and they provide sources of alkalinity in Maryland Coastal Plain watersheds that normally have low alkalinity. This project was designed to 1) compare base flow water chemistry in headwater reaches of urban and non-urban streams, and 2) to evaluate downstream changes in water chemistry in channelized urban streams in comparison with non-urban reference streams. During a drought year, headwater streams in both urban and non-urban sites had significant concentrations of Fe(II) that were discharged from groundwater sources and rapidly oxidized by iron-oxidizing bacteria. During a wet year, the concentrations of Fe(II) were higher in headwater urban streams than in the non-urban streams. This suggests that impervious surfaces in headwater urban watersheds prevent the recharge of oxygen-rich waters during storm events, which maintains iron-rich groundwater discharge to the stream. Downstream changes in water chemistry are prominent in cement-lined urban channels because they are associated with distinctive microbial communities. The headwater zones of channelized streams are dominated by iron-ozidizing bacteria, that are replaced downstream by manganese-oxidizing zones, and replaced further downstream by biofilms dominated by photosynthesizing cyanobacteria. The reaches dominated by cyanobacteria exhibit diurnal changes in pH due to uptake of CO2 for photosynthesis. Diurnal changes range from 7.5 to 8.8 in the summer months to 7.0 to 7.5 in the cooler months, indicating both the impact of photosynthesis and the additional source of alkalinity provided by concrete. The dissolved oxygen, pH, and other characteristics of tributaries dominated by cyanobacteria are similar to the water chemistry characteristics observed in much larger urban river channels further downstream. These downstream redox zonations, microbial habitats, and pH characteristics observed in channelized tributaries are very different from non-urban watersheds in the Maryland Coastal Plain, which have pH values less than 7 and do not have the prominent redox zonations and associated microbial habitats. These downstream changes in redox chemistry and pH in urban stream channels have implications for the transport and retention of heavy metals in urban streams.
DE: 0400 Biogeosciences
DE: 1831 Groundwater quality
DE: 1860 Runoff and streamflow
DE: 1871 Surface water quality
SC: North American Benthological Society [NB]
MN: 2005 Joint Assembly