V43C-01
Unlocking the Secrets of the Mantle Wedge: New Insights Into Melt Generation Processes in Subduction Zones
Recent laboratory studies of the melting and crystallization behavior of mantle peridotite and subduction zone lavas have led to new insights into melting processes in island arc settings. Melting of the mantle wedge in the presence of H2O begins at much lower temperatures than previously thought. The solidus of mantle peridotite at 3 GPa is ~ 800 °C, which is 200 °C below previous estimates. At pressures greater than 2.4 GPa chlorite becomes a stable phase on the solidus and it remains stable until ~ 3.5 GPa. Therefore, melting over this pressure range occurs in the presence of chlorite, which contains ~ 12 wt. % H2O. Chlorite stabilized on the peridotite solidus by slab-derived H2O may be the ultimate source of H2O for subduction zone magmatism. Thus, chlorite could transport large amounts of H2O into the descending mantle wedge to depths where it can participate in melting to generate hydrous arc magmas. Our ability to identify primitive mantle melts at subduction zones has led to the following observations. 1) Primitive mantle melts show evidence of final equilibration at shallow depths near the mantle - crust boundary. 2) They contain variable amounts of dissolved H2O (up to 6 wt. %). 3) They record variable extents of melting (up to > 25 wt. %). To produce melts with such variable characteristics requires more than one melting process and requires consideration of a new type of melting called hydrous flux melting. Flux melting occurs when the H2O - rich melt initially produced on the solidus near the base of the mantle wedge ascends and continuously reacts with overlying hotter, shallower mantle. The mantle melts and magmatic H2O content is constantly diluted as the melt ascends and reacts with shallower, hotter mantle. Anhydrous mantle melts are also found in close temporal and spatial proximity to hydrous flux melts. These melts are extracted at similar depths near the top of the mantle wedge when mantle is advected up and into the wedge corner and melted by adiabatic decompression. In light of these new insights into the chemical processes that lead to melt generation in subduction zones, further study of the influence of mantle dynamics and physical processes on melting is crucial. Variations in mantle permeability near the base of the wedge may exercise important controls on the access of fluids and/or melts to the overlying wedge. The presence of chlorite in the wedge may also influence rheological properties and seismicity in the vicinity of the slab - wedge interface. Improved knowledge of rheology and permeability will help us to develop more robust models of mantle flow and temperature distribution in the mantle wedge. These are crucial for refining melting models. By combining evidence from petrology, geochemistry and geophysics the mysteries that attend the generation of melt in the mantle wedge can be resolved.