HR: 0800h
AN: GP21A-13 [Abstracts]
TI: Compositional, thermal, and orientation dependency of olivine magnetic properties
AU: * Belley, F
EM: fanfan24@siu.edu
AF: Department of Geology, Southern Illinois University, Carbondale, IL 62901, United States
AU: Ferré, E C
EM: eferre@geo.siu.edu
AF: Department of Geology, Southern Illinois University, Carbondale, IL 62901, United States
AU: Martín-Hernández, F
EM: fatima@geo.uu.nl
AF: Paleomagnetic Laboratory ‘Fort Hoofddijk', Utrecht University, Utrecht, 3584 CD,
Netherlands
AU: Jackson, M J
EM: irm@umn.edu
AF: Institute for Rock Magnetism, University of Minnesota, Minneapolis, MN 55455, United
States
AU: Dyar, M D
EM: mddyar@amherst.edu
AF: Mount Holyoke College, Clapp 320, 50 College Street, South Hadley, MA 01075, United
States
AU: Catlos, E J
EM: catlos@okstate.edu
AF: Oklahoma State University, School of Geology, 105 Noble Research Centre, Stillwater, OK
74078, United States
AB:
Olivine is an orthosilicate solid solution between forsterite Mg2SiO4 (Fo100) and fayalite Fe2SiO4
(Fo0). Cations such as Si4+ and Mg2+ are responsible for the diamagnetic behavior, whereas
Fe2+ and other cations, present as defects in the lattice, such as Fe3+, Cr2+, and Mn2+,
contributes to the paramagnetic behavior of the olivine. Yet, most natural and even synthetic olivines contain
ferromagnetic iron oxide exsolutions similar to those commonly reported in other mafic silicates.
Olivine is one of the most abundant constituents in the upper mantle of rocky planets, in meteorites, and in
cosmic dust. Olivines with composition ranging form Fo100 to Fo0 are then exposed to temperatures
that vary widely from about 5 K, away from the Sun in space, to about 1773 K at the 410 km olivine-wadsleyite
transition. Below the Néel temperature (TN< 65 K), natural and synthetic fayalites exhibit a magnetic
transition interpreted as the change from paramagnetic to antiferromagnetic behavior. A second low-temperature
transition has been described around 20 K in fayalite and was attributed to a change from collinear to canted
antiferromagnetic state. The magnetic properties of fayalite are also varying with crystal orientation. At decreasing
temperature, just below TN, the magnetic susceptibility along the b axis stops following the Curie-Weiss law
and begins to decrease. This drastic change is a clear indication of the antiferromagnetic behavior. The variation
of magnetic susceptibility as a function of decreasing temperature along the two other axes, a and c, remains
practically constant through the Néel transition. At the second low temperature transition (Tt), around 23 K, the
variation of magnetic susceptibility with temperature changes along the c axis whereas no changes are noted
along a and b.
Experiments were performed on natural and synthetic ferromagnesian olivines of various iron contents between 4
and 300 K to further investigate their magnetic properties, regarding low-temperature transitions, compositional
dependency, and magnetic anisotropy. Measurements were carried out in high magnetic fields, above the
saturation of the ferromagnetic exsolutions to get access to the paramagnetic or diamagnetic properties of
olivine.
DE: 1518 Magnetic fabrics and anisotropy
DE: 1519 Magnetic mineralogy and petrology
DE: 1540 Rock and mineral magnetism
DE: 3900 MINERAL PHYSICS
DE: 5400 PLANETARY SCIENCES: SOLID SURFACE PLANETS
SC: Geomagnetism and Paleomagnetism [GP]
MN: 2007 Joint Assembly